One of the six-membered rings adopts a screw-boat conformation, one adopts an envelope conformation and the third is planar. N hydrogen-bonding interactions contribute to the stability of the structure.
The pyrazole ring is in an envelope conformation.
N hydrogen bonds, leading to a chain structure. O hydrogen bonds to form centrosymmetric hydrogen-bonded dimers. N hydrogen bonds together with weak N.
The structure consists of chains running along the a axis. The crystals were found to be twinned.
The are two molecules in the asymmetric unit. O hydrogen bonds that link adjacent molecules into one-dimensional extended chains.
The CdII ion and the phenanthroline ligand are positioned on a twofold axis.
I edges, thus giving rise to a polymeric chain along the c axis. The triazole ring is almost coplanar with the pyrimidine ring.
O hydrogen bonds are observed. A three-dimensional supramolecular architecture is formed via hydrogen-bond interactions.
The two symmetry-independent Co atoms show a cis-octahedral coordination.
The Ni atom lies on a centre of symmetry. I edges, thus giving rise to a polymeric chain along the c axis.
O hydrogen bonds link adjacent complex molecules via the uncoordinated water molecules into a three-dimensional network architecture. The structure consists of chains running along the a axis.
N hydrogen bonds together with weak N.
O hydrogen bonds that link adjacent molecules into one-dimensional extended chains.
Each ligand provides one O atom and one N atom.
O hydrogen bonds link the molecules, forming a network, which may be effective in the stabilization of the crystal structure. O hydrogen bond involving the NH imine H atom and the phenolate O atom.
There is a centre of symmetry at the centre of each cation ring.
The sandine framework consists of two five- and three six-membered condensed rings.
O hydrogen bonds to form layers.