Hi,
I tried to export to pdf with the following:
#+LATEX_HEADER: \usepackage{polyglossia}
#+LATEX_HEADER: \usepackage{fontspec}
#+LATEX_COMPILER: xelatex (also tried with lualatex)
#+LATEX_HEADER: \setmainlanguage{english}
#+LATEX_HEADER: \setotherlanguage{sanskrit}
#+LATEX_HEADER: \newfontfamily\devanagarifont{Noto Serif Devanagari}
स्वस्ति सत्यं वचति
but it exports alright to odt, and even pandoc exports alright directly from org file to docx file, but the Sanskrit/Devanagari fonts are skipped (blank) in pdf output when exported directly from org file with C-c C-e l o.